6.25 Listed below are several hypothetical nucleophilic
substitution reactions. None is synthetically useful because the
product indicated is not formed at an appreciable rate. In each
case provide an explanation for the failure of the reaction to take
place as indicated.
(Problems A, B, D, and E needed)
o. With methyl, ethyl, or cyclopentyl halides as your organic starting materials and using any needed solvents or earlier parts outline in syntheses of each of the following More than one step may be necessary and you need not repeat steps carried out of this problem. (a) CH (e) CH3SH CHaOCH (b) OMe SH (g) CH3CN (c) CH3OH (k) (d) (h) CN OH 6.25 Listed below are several hypothetical nucleophilic substitution reactions. None is synthetically useful to the p as roduct indicated is not formed at an appreciable rate. In each case provide an explanation for the failure of the reaction take place indicated. (a) HOT OH CH OH (b) (c) OH Br (d) CN Br (e) NHla CH3OCH3 CH3NH CHaOH (f) NH CHOH CH3NH3 H2O 6.26 Your task is to prepare by one of the following reactions. Which reaction would you choose to give the better yield of ne styrene? Explain your answer. Br KOH KOH (2) or EtOH, A EtOH, A Styrene Styrene 6.27 Your prepare isopropyl methyl ether by one of the following reactions. Which reaction would give the better yiel task is to Explain your answer.
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